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Various

"Scientific American Supplement, No. 623, December 10, 1887"

A. & L. Brin, who had
studied chemistry under Boussingault, undertook experiments with the
view of determining why the baryta lost its power of absorbing oxygen.
They found that it was owing to molecular and physical changes caused
in it by impurities in the air used and by the high temperature
employed for decomposing the dioxide. They discovered that by heating
the dioxide in a partial vacuum the temperature necessary to drive off
its oxygen was much reduced. They also found that by supplying the air
to the baryta under a moderate pressure, its absorption of oxygen was
greatly assisted. Under these conditions, and by carefully purifying
the air before use, they found that it became possible to use the
baryta an indefinite number of times. Thus the process became
practically, as it was theoretically, continuous.
After securing patent protection for their process, Messrs. Brin
erected a small producer in Paris, and successfully worked it for
nearly three years without finding a renewal of the original charge of
baryta once necessary. This producer was exhibited at the Inventions
Exhibition in London, in 1885. Subsequently an English company was
formed, and in the autumn of last year Brin's Oxygen Company began
operations in Horseferry Road, Westminster, where a large and complete
demonstration plant was erected, and the work commenced of developing
the production and application of oxygen in the industrial world.


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