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Various

"Scientific American Supplement, No. 455, September 20, 1884"

Further, for the formation
of this hydrogen compound by the fermentation of the starch, or by the
growth of minute fungi, the _entire_ compound must be broken up, and
therefore the pigment would become discolored; but aceto-arsenite of
copper
(3CuAs_{2}O_{4}+Cu(C_{2}H_{3}O_{2})_{2})
is a very stable compound, not readily undergoing decomposition, and is
consequently a very permanent color. It has also been not unfrequently
stated that the injurious effects of this pigment are due to the arsenious
oxide volatilizing from the other constituents of the compound. This
volatilization would likewise cause a breaking up of the entire compound,
and would consequently cause a discoloration of the paper; but the
volatilization of this arsenic compound is in every respect most
improbable.
The injurious effects, if any, of this pigment must therefore be due to
its mechanical detachment from the paper; but has it ever been
conclusively proved that persons who inhabit rooms the wall-paper of which
is stained with emerald-green suffer from arsenical poisoning? If it does
occur, then the effects of what may be termed homoeopathic doses of this
substance are totally different from the effects which arise from larger
doses. During the packing of this substance in its dry state in the
factory, clouds of its dust ascend in the air, and during the time I had
to do with its manufacture I never heard that any of the factory hands
suffered, nor did I suffer, from arsenical poisoning.


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